I've learned quite a bit tonight, I think. I started out tinkering with a static OC for use in conjunction with the C8DH's dynamic OC feature. What I believe I learned is that it's relatively easy to setup a static OC that will throw out some big numbers in CBR23 (31,500+ for MT) or CPU-Z, but if we try to tune the static OC for a worst-case scenario (I used prime95/small FFT/with AVX/AVX2 enabled), by the time we get the overclock stable and thermally manage able our increased performance has evaporated. Since AMD based systems don't have an AVX offset, that I'm aware of, the options seem somewhat limited. I have the impression that at the end of the day, PBO2 and its management algorithm keep all the really handy adjustment dials hidden behind the curtain.
My self-imposed goal of a maximum overclock that is 100% daily driving safe and stable (even under less than likely usage cases like the prime95 configuration indicated above) hasn't changed. So, at this point I plan to chuck ASUS's DOC feature out with the bath water, rollback to an older driver, and try again with just PBO2. I can imagine specific use cases where DOC switching might be advantageous, but I don't believe they currently apply to me.
I'll try to summarize some of the behavior I observed from my system tonight. I maxed out my ambient cooling capabilities at 303W. This loading was achieved using the indicated prime95 configuration. Other settings included 1.35 VID set / 1.203 VID get (LLC 2). HWiNFO64 indicated a peak "CPU" temperature of 82⁰C, but I had a peak core temperature of 94.5⁰C. CCD0 clocked @ 4.5GHZ and CCD1 @ 4.45GHZ. At these settings, I was scoring around 30,150 in CBR23. I think my previous best was 30,500ish with PBO2 (admittedly with a less than 100% stable CPU, but no RAM tune to speak of). I think I can claw my way back to the 30,500 neighborhood with rock solid stability given time. Wish me luck .
P.S. I'm don't doubt a liquid metal application between CPU die and waterblock could assist me, but I'm not in the mood to drain and dismantle the loop again currently. I certainly do get the appeal of quick disconnect fittings now, even if they do introduce a little more flow restriction.